Search results for "peroxidase activity"

showing 3 items of 3 documents

A Thermophilic Tetramolecular G-Quadruplex/Hemin DNAzyme.

2017

International audience; The quadruplex-based DNAzyme system is one of the most useful artificial enzymes or catalysts; their unique properties make them reliable alternatives to proteins for performing catalytic transformation. The first prototype of a thermally stable DNAzyme system is presented. This thermophilic DNAzyme is capable of oxidizing substrates at high temperatures (up to 95 degrees C) and long reaction times (up to 18 h at 75 degrees C). The catalytic activity of the DNAzymes were investigated with the standard peroxidase-mimicking oxidation of 2,2'-azino-bis(3-ethylbenzothiozoline-6-sulfonic acid) (ABTS) by H2O2. The step-by-step design of this unique heat-activated G-quadrup…

Catalytic transformationDNAzymeoxidationDeoxyribozymeaptamersspecificityNanotechnologyBiocompatible MaterialsdnainsightsG-quadruplex010402 general chemistry[ CHIM ] Chemical Sciences01 natural sciencesperoxidase-mimicking dnazymesCatalysisCatalysischemistry.chemical_compoundOxidizing agent[CHIM]Chemical SciencesBenzothiazolesthermophilicityComputingMilieux_MISCELLANEOUSPeroxidaseChemistry010405 organic chemistryThermophileperoxidase activityGeneral Chemistry[CHIM.CATA]Chemical Sciences/CatalysisGeneral MedicineDNA CatalyticHydrogen PeroxideCombinatorial chemistry0104 chemical sciencesG-QuadruplexesMethylene BluekineticsHeminactivity enhancementSulfonic AcidsporphyrinOxidation-ReductioncomplexHeminAngewandte Chemie (International ed. in English)
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Gold Nanoparticles Supported on Nanoparticulate Ceria as a Powerful Agent against Intracellular Oxidative Stress

2012

Ceria-supported gold nanoparticles are prepared exhibiting peroxidase activity and acting as radical traps. Au/CeO2 shows a remarkable biocompatibility as demonstrated by measuring cellular viability, proliferation, and lack of apoptosis for two human cell lines (Hep3B and HeLa). The antioxidant activity of Au/CeO2 against reactive oxygen species (ROS) is demonstrated by studying the cellular behavior of Hep3B and HeLa in a model of cellular oxidative stress. It is determined that Au/CeO2 exhibits higher antioxidant activity than glutathione, the main cytosolic antioxidant compound, and its CeO2 carrier. Overall the result presented here shows the potential of implementing well-established …

Time FactorsAntioxidantMaterials scienceBiocompatibilityCell SurvivalPolymersPeroxidase activitymedicine.medical_treatmentMetal NanoparticlesApoptosisBiocompatible MaterialsIntracellular oxidative stressmedicine.disease_causeAntioxidantsCatalysisCell LineBiomaterialsHeLachemistry.chemical_compoundCeriaQUIMICA ORGANICAmedicineHumansNanotechnologyGold nanoparticlesGeneral Materials ScienceCell Proliferationchemistry.chemical_classificationReactive oxygen speciesbiologyGeneral ChemistryGlutathionebiology.organism_classificationOxidative StressNanomedicinePeroxidasesBiochemistrychemistryColloidal goldNanoparticlesGoldReactive Oxygen SpeciesIntracellularOxidative stressHeLa CellsBiotechnologySmall
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Glutathione Peroxidase Activity and Selenium Therapy in Muscular Dystrophies

1988

chemistryBiochemistrychemistry.chemical_elementGeneral MedicineGlutathione peroxidase activitySeleniumClinical Science
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